Customising your Geochemistry

As we all know, no two deposits geochemistry are exactly alike. Each one comes with its own unique characteristics and challenges. Defining the geochemistry of a deposit is a critical step that often requires a significant amount of time and expense. In the past decade, the use of portable XRF (pXRF) instruments to provide rapid in-field quantification of a sample’s geochemistry, has revolutionised the way we approach defining a deposits geochemistry. Portable XRF instruments are not designed to replace lab assaying, instead they enable real time decision making and provide a first pass screening method to reduce the number of samples that need to be sent to the lab.

The accuracy of portable XRF results fundamentally depends on how well a calibration suits the mineral matrix of the samples. While a range of different calibrations are available from manufacturers, off-the-shelf instruments are often restricted to a manufacturer’s universal calibrations. These calibrations are developed to be a general tool for as wide a range of elements and concentrations as possible and are often fit for purpose. However, they generally do not allow flexibility to adjust to varying sample matrices, a common situation in geological environments. To overcome this restriction, custom calibrations are required.

Custom calibrations can be generated for Bruker S1 TITAN,  CTX and TRACER 5 series instruments, as the software allows back end access by the user to generate their own calibrations. Custom calibrations can be invaluable to improve the results generated by a portable XRF and provide reliable analyses. Some reasons a custom calibration may be necessary are:

  • A higher accuracy for a certain element in required e.g., when the data needs to be within 10% of the certified concentration, rather than the standard 20% provided by off-the-shelf calibrations.
  • The deposit has an unusual matrix that the off-the-shelf calibration is not calculated for.
  • An element is of critical importance and is not included in the off-the-shelf calibration.
  • A target element is outside of the concentration range captured by the off-the-shelf calibration.

Custom calibrations can be generated from a mixture of client samples and carefully selected standards to optimise for the specific mineral matrix.

Geochemistry Case Study

A case study of where a custom calibration was identified to be necessary was observed while measuring caesium (Cs) using the GeoExploration calibration on a Bruker S1 TITAN. When using the off-the-shelf calibration low levels of Cs were reported which was noteworthy, but not particularly outstanding. When the samples came back from the lab however, the assay results showed astonishingly high levels of Cs (Figure 1). The underreporting of Cs by the pXRF was due to the lack of any available commercial high grade Cs standards being included in the general off-the-shelf calibration. The off-the-shelf calibration could not extrapolate to accurately quantify Cs at higher concentrations.  Client samples were used to generate a custom calibration for a Cs-rich deposit which significantly improved the ability to accurately quantify Cs with in-field portable XRF analysis.

graph showing portable XRF geochemistry

Figure 1. Caesium assay results compared with pXRF results using an off-the-shelf calibration.

Figure 2. Caesium assay results compared with pXRF results using a custom calibration.

Portable Spectral Services have created several in-house custom calibrations that include, but are not limited to:

  • Lithium calibrations
  • Vanadium calibrations
  • Sodium calibrations
  • Scandium calibrations
  • Concentrate calibrations

For more information on custom calibrations head to Custom Calibrations or email send us an email!

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